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CONCRETE 101 - Massachusetts |
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Concrete
History Composition
Concrete Production
Damage Modes
Types of Concrete Concrete
Recycling |
Concrete
is a construction material composed of
cement (commonly
Portland cement) as well as other cementitious
materials such as
fly ash and
slag cement,
aggregate (generally a coarse aggregate such as
gravel,
limestone, or
granite, plus a fine aggregate such as
sand),
water, and
chemical admixtures. The word concrete comes from
the Latin word "concretus", which means "hardened" or
"hard".Concrete
solidifies and hardens after mixing with water and
placement due to a
chemical process known as
hydration. The water reacts with the cement, which
bonds the other components together, eventually creating
a stone-like material. Concrete is used to make
pavements,
architectural structures,
foundations,
motorways/roads,
bridges/overpasses,
parking structures,
brick/block
walls and
footings for gates,
fences and
poles.
Concrete is used more
than any other man-made material in the world.[1]
As of 2006, about 7.5 cubic kilometres of concrete are
made each year—more than one cubic metre for every
person on Earth.[2]
Concrete powers a
US $35-billion industry which employs more than two
million workers in the
United States alone.More than 55,000 miles
(89,000 km) of
highways in America are paved with this material.
The
People's Republic of China currently consumes 40% of
the world's cement/concrete production.
Reinforced concrete and
Prestressed concrete are the most widely used
modern kinds of concrete functional extensions.
From Wikipedia, the free encyclopedia.
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History
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Many ancient civilizations
used forms of concrete using dried mud, straw, and other
materials.
During the
Roman Empire,
Roman concrete was made from
quicklime,
pozzolanic ash/pozzolana,
and an aggregate of
pumice; it was very similar to modern Portland
cement concrete. The widespread use of concrete in many
Roman structures has ensured that many survive almost
intact to the present day. The
Baths of Caracalla in
Rome are just one example of the longevity of
concrete, which allowed the Romans to build this and
similar structures across the Roman Empire. Many
Roman aqueducts have masonry cladding to a concrete
core, a technique they used in structures such as the
Pantheon, the dome of which is concrete.
The secret of
concrete was lost for 13 centuries until 1756, when the
British engineer
John Smeaton pioneered the use of
hydraulic lime in concrete, using pebbles and
powdered brick as aggregate.
Portland cement was first used in concrete in the
early 1840s. This version of history has been challenged
however, as the
Canal du Midi was constructed using concrete in
1670.[3]
Recently, the use of
recycled materials as concrete ingredients is gaining
popularity because of increasingly stringent
environmental legislation. The most conspicuous of these
is
fly ash, a by-product of
coal-fired power plants. This has a significant
impact by reducing the amount of quarrying and landfill
space required, and, as it acts as a cement replacement,
reduces the amount of cement required to produce a solid
concrete. As cement production creates massive
quantities of carbon dioxide, cement-replacement
technology such as this will play an important role in
future attempts to cut
carbon dioxide emissions.
Concrete additives have
been used since Roman and Egyptian times, when it was
discovered that adding volcanic ash to the mix allowed
it to set under water. Similarly, the Romans knew that
adding
horse hair made concrete less liable to crack while
it hardened, and adding blood made it more
frost-resistant[4].
In modern times,
researchers have experimented with the addition of other
materials to create concrete with improved properties,
such as higher strength or electrical conductivity.
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Composition
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There are many
types of concrete available, created by varying the
proportions of the main ingredients below.
The
mix design depends on the type of structure
being built, how the concrete will be mixed and
delivered, and how it will be placed to form this
structure.
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Cement
Portland cement is the most common type of cement in
general usage. It is a basic ingredient of concrete,
mortar, and
plaster. English engineer
Joseph Aspdin patented Portland cement in 1824; it
was named because of its similarity in colour to
Portland limestone, quarried from the English
Isle of Portland and used extensively in
London architecture. It consists of a mixture of
oxides of
calcium,
silicon and
aluminium. Portland cement and similar materials are
made by heating
limestone (a source of calcium) with clay, and
grinding this product (called
clinker) with a source of
sulfate (most commonly
gypsum). The manufacturing of Portland cement
creates about 5 percent of human CO2 emissions.[5]
Water
Combining water with a
cementitious material forms a cement paste by the
process of hydration. The cement paste glues the
aggregate together, fills voids within it, and allows it
to flow more easily.
Less water in the
cement paste will yield a stronger, more durable
concrete; more water will give an easier-flowing
concrete with a higher
slump.[6]
Impure water used to
make concrete can cause problems, when setting, or in
causing premature failure of the structure.
Hydration involves many
different reactions, often occurring at the same time.
As the reactions proceed, the products of the cement
hydration process gradually bond together the individual
sand and gravel particles, and other components of the
concrete, to form a solid mass.
Reaction:
-
Cement chemist notation: C3S + H2O → CSH(gel) +
CaOH
- Standard notation:
Ca3SiO5 + H2O → (CaO)•(SiO2)•(H2O)(gel) + Ca(OH)2
- Balanced: 2Ca3SiO5
+ 7H2O → 3(CaO)•2(SiO2)•4(H2O)(gel) + 3Ca(OH)2
Aggregates
Fine and coarse
aggregates make up the bulk of a concrete mixture.
Sand, natural gravel and
crushed stone are mainly used for this purpose.
Recycled aggregates (from construction, demolition and
excavation waste) are increasingly used as partial
replacements of natural aggregates, while a number of
manufactured aggregates, including air-cooled
blast furnace slag and
bottom ash are also permitted.
Decorative stones such
as
quartzite, small river stones or crushed glass are
sometimes added to the surface of concrete for a
decorative "exposed aggregate" finish, popular among
landscape designers.
Reinforcement
Concrete is strong in
compression, as the aggregate efficiently carries
the compression load. However, it is weak in tension as
the cement holding the aggregate in place can crack,
allowing the structure to fail.
Reinforced concrete solves these problems by adding
either
metal reinforcing bars, glass fiber, or plastic
fiber to carry
tensile loads.
Chemical admixtures
Chemical admixtures are materials in the form of
powder or fluids that are added to the concrete to give
it certain characteristics not obtainable with plain
concrete mixes. In normal use, admixture dosages are
less than 5% by mass of cement, and are added to the
concrete at the time of batching/mixing.[7]
The most common types of admixtures
[8] are:
-
Accelerators speed up the hydration (hardening)
of the concrete. Typical materials used are CaCl2
and NaCl.
-
Retarders slow the hydration of concrete, and
are used in large or difficult pours where partial
setting before the pour is complete is undesirable.
A typical retarder is sugar (C6H12O6).
-
Air entrainments add and distribute tiny air
bubbles in the concrete, which will reduce damage
during
freeze-thaw cycles thereby increasing the
concrete's durability. However, entrained air is a
trade-off with strength, as each 1% of air may
result in 5% decrease in compressive strength.
-
Plasticizers (water-reducing admixtures)
increase the workability of plastic or "fresh"
concrete, allowing it be placed more easily, with
less consolidating effort. Superplasticizers
(high-range water-reducing admixtures) are a class
of plasticizers which have fewer deleterious effects
when used to significantly increase workability.
Alternatively, plasticizers can be used to reduce
the water content of a concrete (and have been
called water reducers due to this application) while
maintaining workability. This improves its strength
and durability characteristics.
-
Pigments can be used to change the color of
concrete, for aesthetics.
-
Corrosion inhibitors are used to minimize the
corrosion of steel and steel bars in concrete.
- Bonding agents are
used to create a bond between old and new concrete.
- Pumping aids
improve pumpability, thicken the paste, and reduce
dewatering – the tendency for the water to separate
out of the paste.
Mineral admixtures and
blended cements
There are inorganic
materials that also have
pozzolanic or latent hydraulic properties. These
very
fine-grained materials are added to the concrete mix
to improve the properties of concrete (mineral
admixtures),[7]
or as a replacement for Portland cement (blended
cements).[9]
-
Fly ash: A by product of coal fired
electric generating plants, it is used to
partially replace Portland cement (by up to 60% by
mass). The properties of fly ash depend on the type
of coal burnt. In general, silicious fly ash is
pozzolanic, while
calcareous fly ash has latent hydraulic
properties.[10]
-
Ground granulated blast furnace slag (GGBFS or
GGBS): A by product of
steel production, is used to partially replace
Portland cement (by up to 80% by mass). It has
latent hydraulic properties.[11]
-
Silica fume: A by-product of the production of
silicon and
ferrosilicon alloys. Silica fume is similar to
fly ash, but has a particle size 100 times smaller.
This results in a higher surface to volume ratio and
a much faster
pozzolanic reaction. Silica fume is used to
increase strength and durability of concrete, but
generally requires the use of superplasticizers for
workability.[12]
- High Reactivity
Metakaolin (HRM): Metakaolin produces concrete
with strength and durability similar to concrete
made with silica fume. While silica fume is usually
dark gray or black in color, high reactivity
metakaolin is usually bright white in color, making
it the preferred choice for architectural concrete
where appearance is important.
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Concrete Production
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The processes used vary
dramatically, from hand tools to heavy industry, but
result in the concrete being placed where it cures into
a final form.
When initially mixed
together, Portland cement and water rapidly form a
gel, formed of tangled chains of interlocking
crystals. These continue to react over time, with the
initially fluid gel often aiding in placement by
improving workability. As the concrete sets, the chains
of crystals join up, and form a rigid structure, gluing
the aggregate particles in place. During curing, more of
the cement reacts with the residual water (Hydration).
This curing process
develops physical and
chemical properties. Among other qualities,
mechanical strength, low moisture permeability, and
chemical and volumetric stability.
Mixing
Concrete
Thorough
mixing is essential for the production
of uniform, high quality concrete.
Therefore, equipment and methods should
be capable of effectively mixing
concrete materials containing the
largest specified aggregate to produce
uniform mixtures of the lowest slump
practical for the work. Separate paste
mixing has shown that the mixing of
cement and water into a paste before
combining these materials with
aggregates can increase the
compressive strength of the
resulting concrete.[13]
The paste is generally mixed in a
high-speed, shear-type mixer at a
w/cm (water to cement ratio) of 0.30
to 0.45 by mass. The cement paste premix
may include admixtures, e.g.
accelerators or retarders, plasticizers,
pigments, or fumed
silica. The latter is added to fill
the gaps between the cement particles.
This reduces the particle distance and
leads to a higher final compressive
strength and a higher water
impermeability.[14]
The premixed paste is then blended with
aggregates and any remaining batch
water, and final mixing is completed in
conventional concrete mixing equipment.[15]
High-Energy Mixed Concrete (HEM
concrete) is produced by means of
high-speed mixing of cement, water and
sand with net
specific energy consumption at least
5 kilojoules per kilogram of the mix. It
is then added to a
plasticizer admixture and mixed
after that with aggregates in
conventional
concrete mixer. This paste can be
used itself or foamed (expanded) for
lightweight concrete.[16]
Sand effectively dissipates energy in
this mixing process. HEM concrete fast
hardens in ordinary and low temperature
conditions, and possesses increased
volume of gel, drastically reducing
capillarity in solid and porous
materials. It is recommended for precast
concrete in order to reduce quantity of
cement, as well as concrete roof and
siding tiles, paving stones and
lightweight concrete block production
Workability
Workability is the
ability of a fresh
(plastic) concrete mix
to fill the form/mold
properly with the
desired work (vibration)
and without reducing the
concrete's quality.
Workability depends on
water content,
aggregate (shape and
size distribution),
cementitious content and
age (level of
hydration), and can
be modified by adding
chemical admixtures.
Raising the water
content or adding
chemical admixtures will
increase concrete
workability. Excessive
water will lead to
increased bleeding (surface
water) and/or
segregation of
aggregates (when the
cement and aggregates
start to separate), with
the resulting concrete
having reduced quality.
The use of an aggregate
with an undesirable
gradation can result in
a very harsh mix design
with a very low slump,
which cannot be readily
made more workable by
addition of reasonable
amounts of water.
Workability can be
measured by the
Concrete Slump Test,
a simplistic measure of
the plasticity of a
fresh batch of concrete
following the
ASTM C 143 or EN
12350-2 test standards.
Slump is normally
measured by filling an "Abrams
cone" with a sample
from a fresh batch of
concrete. The cone is
placed with the wide end
down onto a level,
non-absorptive surface.
It is then filled in
three layers of equal
volume, with each layer
being tamped with a
steel rod in order to
consolidate the layer.
When the cone is
carefully lifted off,
the enclosed material
will slump a certain
amount due to gravity. A
relatively dry sample
will slump very little,
having a slump value of
one or two inches (25 or
50 mm). A relatively wet
concrete sample may
slump as much as six or
seven inches (150 to 175
mm).
Slump can be increased
by adding chemical
admixtures such as
mid-range or
high-range water
reducing agents
(super-plasticizers)
without changing the
water/cement ratio.
It is bad practice to
add excessive water upon
delivery to the jobsite,
however in a properly
designed mixture it is
important to reasonably
achieve the specified
slump prior to placement
as design factors such
as air content, internal
water for
hydration/strength gain,
etc. are dependent on
placement at design
slump values.
High-flow concrete, like
self-consolidating
concrete, is tested
by other flow-measuring
methods. One of these
methods includes placing
the cone on the narrow
end and observing how
the mix flows through
the cone while it is
gradually lifted.
Curing
In all but the least
critical applications,
care needs to be taken
to properly cure
concrete, and achieve
best strength and
hardness. This happens
after the concrete has
been placed. Cement
requires a moist,
controlled environment
to gain strength and
harden fully. The cement
paste hardens over time,
initially setting and
becoming rigid though
very weak, and gaining
in strength in the days
and weeks following. In
around 3 weeks, over 90%
of the final strength is
typically reached though
it may continue to
strengthen for decades.[17]
Hydration and hardening
of concrete during the
first three days is
critical. Abnormally
fast drying and
shrinkage due to factors
such as evaporation from
wind during placement
may lead to increased
tensile stresses at a
time when it has not yet
gained significant
strength, resulting in
greater shrinkage
cracking. The early
strength of the concrete
can be increased by
keeping it damp for a
longer period during the
curing process.
Minimizing stress prior
to curing minimizes
cracking. High
early-strength concrete
is designed to hydrate
faster, often by
increased use of cement
which increases
shrinkage and cracking.
During this period
concrete needs to be in
conditions with a
controlled temperature
and humid atmosphere. In
practice, this is
achieved by spraying or
ponding the concrete
surface with water,
thereby protecting
concrete mass from ill
effects of ambient
conditions. The pictures
to the right show two of
many ways to achieve
this, ponding –
submerging setting
concrete in water, and
wrapping in plastic to
contain the water in the
mix.
Properly curing concrete
leads to increased
strength and lower
permeability, and avoids
cracking where the
surface dries out
prematurely. Care must
also be taken to avoid
freezing, or overheating
due to the
exothermic setting
of cement (the
Hoover Dam used
pipes carrying coolant
during setting to avoid
damaging overheating).
Improper curing can
cause scaling, reduced
strength, poor abrasion
resistance and cracking.
Strength
Concrete has relatively
high
compressive strength,
but significantly lower
tensile strength. It
is fair to assume that a
concrete sample's
tensile strength is
about 10%-15% of its
compressive strength.[18]
As a result, without
compensating, concrete
would almost always fail
from tensile stresses –
even when loaded in
compression. The
practical implication of
this is that concrete
elements subjected to
tensile stresses must be
reinforced with
materials that are
strong in tension.
Reinforced concrete
is the most common form
of concrete. The
reinforcement is often
steel,
rebar (mesh, spiral,
bars and other forms).
Structural fibers of
various materials are
available.
Concrete can also be
prestressed
(reducing
tensile stress)
using internal steel
cables (tendons),
allowing for
beams or slabs with
a longer
span than is
practical with
reinforced concrete
alone. Inspection of
concrete structures can
be non-destructive if
carried out with
equipment such as a
Schmidt hammer,
which is used to
estimate concrete
strength.
The ultimate strength of
concrete is influenced
by the water-cementitious
ratio (w/cm), the design
constituents, and the
mixing, placement and
curing methods employed.
All things being equal,
concrete with a lower
water-cement (cementitious)
ratio makes a stronger
concrete than that with
a higher ratio. The
total quantity of
cementitious materials
(Portland cement, slag
cement, pozzolans) can
affect strength, water
demand, shrinkage,
abrasion resistance and
density. All concrete
will crack independent
of whether or not it has
sufficient compressive
strength. In fact, high
Portland cement content
mixtures can actually
crack more readily due
to increased hydration
rate. As concrete
transforms from its
plastic state, hydrating
to a solid, the material
undergoes shrinkage.
Plastic shrinkage cracks
can occur soon after
placement but if the
evaporation rate is high
they often can actually
occur during finishing
operations, for example
in hot weather or a
breezy day. In very high
strength concrete
mixtures (greater than
10,000 psi) the crushing
strength of the
aggregate can be a
limiting factor to
the ultimate compressive
strength. In lean
concretes (with a high
water-cement ratio) the
crushing strength of the
aggregates is not so
significant.
The internal forces in
common shapes of
structure, such as
arches,
vaults, columns and
walls are predominantly
compressive forces, with
floors and pavements
subjected to tensile
forces. Compressive
strength is widely used
for specification
requirement and quality
control of concrete. The
engineer knows his
target tensile
(flexural) requirements
and will express these
in terms of compressive
strength.
Wired.com reported on
April 13,
2007 that a team
from the
University of Tehran,
competing in a contest
sponsored by the
American Concrete
Institute,
demonstrated several
blocks of concretes with
abnormally high
compressive strengths
between 50,000 and
60,000 PSI at 28 days.[19]
The blocks appeared to
use an aggregate of
steel fibres and
quartz – a mineral
with a compressive
strength of 160,000 PSI,
much higher than typical
high-strength aggregates
such as
granite
(15,000-20,000 PSI).
Elasticity
The modulus of
elasticity of concrete
is a function of the
modulus of elasticity of
the aggregates and the
cement matrix and their
relative proportions.
The modulus of
elasticity of concrete
is relatively constant
at low stress levels but
starts decreasing at
higher stress levels as
matrix cracking
develops. The elastic
modulus of the hardened
paste may be in the
order of 10-30 GPa and
aggregates about 45 to
85 GPa. The concrete
composite is then in the
range of 30 to 50 GPa.
The
American Concrete
Institute allows the
modulus of elasticity to
be calculated using the
following equation:[18]
-
(psi)
where
-
wc = weight of
concrete (pounds per
cubic foot) and
where
-
f'c = compressive
strength of concrete
at 28 days (psi)
This equation is
completely empirical and
is not based on theory.
Note that the value of
Ec found is in units of
psi. For normalweight
concrete (defined as
concrete with a wc of
150 pcf) Ec is permitted
to be taken as
.
Expansion and shrinkage
Concrete has a very low
coefficient of thermal
expansion. However,
if no provision is made
for expansion, very
large forces can be
created, causing cracks
in parts of the
structure not capable of
withstanding the force
or the repeated cycles
of
expansion and
contraction.
As concrete matures it
continues to shrink, due
to the ongoing reaction
taking place in the
material, although the
rate of shrinkage falls
relatively quickly and
keeps reducing over time
(for all practical
purposes concrete is
usually considered to
not shrink due to
hydration any further
after 30 years). The
relative shrinkage and
expansion of concrete
and brickwork require
careful accommodation
when the two forms of
construction interface.
Because concrete is
continuously shrinking
for years after it is
initially placed, it is
generally accepted that
under thermal loading it
will never expand to its
originally placed volume
Cracking
All concrete structures
will crack to some
extent. One of the early
designers of reinforced
concrete,
Robert Maillart,
employed reinforced
concrete in a number of
arched bridges. His
first bridge was simple,
using a large volume of
concrete. He then
realized that much of
the concrete was very
cracked, and could not
be a part of the
structure under
compressive loads, yet
the structure clearly
worked. His later
designs simply removed
the cracked areas,
leaving slender,
beautiful concrete
arches. The
Salginatobel Bridge
is an example of this.
Concrete cracks due to
tensile stress induced
by shrinkage or stresses
occurring during setting
or use. Various means
are used to overcome
this.
Fiber reinforced
concrete uses fine
fibers distributed
throughout the mix or
larger
metal or other
reinforcement
elements to limit the
size and extent of
cracks. In many large
structures joints or
concealed saw-cuts are
placed in the concrete
as it sets to make the
inevitable cracks occur
where they can be
managed and out of
sight. Water tanks and
highways are examples of
structures requiring
crack control.
Shrinkage cracking
Shrinkage cracks occur
when concrete members
undergo restrained
volumetric changes
(shrinkage) as a result
of either drying,
autogenous shrinkage or
thermal effects.
Restraint is provided
either externally (i.e.
supports, walls, and
other boundary
conditions) or
internally (differential
drying shrinkage,
reinforcement). Once the
tensile strength of the
concrete is exceeded, a
crack will develop. The
number and width of
shrinkage cracks that
develop are influenced
by the amount of
shrinkage that occurs,
the amount of restraint
present and the amount
and spacing of
reinforcement provided.
Plastic-shrinkage cracks
are immediately
apparent, visible within
0 to 2 days of
placement, while
drying-shrinkage cracks
develop over time.
Autogenous shrinkage
also occurs when the
concrete is quite young
and results from the
volume reduction
resulting from the
chemical reaction of the
portland cement
Tension cracking
Concrete members may be
put into tension by
applied loads. This is
most common in concrete
beams where a
transversely applied
load will put one
surface into compression
and the opposite surface
into tension due to
induced
bending. The portion
of the beam that is in
tension may crack. The
size and length of
cracks is dependent on
the magnitude of the
bending moment and the
design of the
reinforcing in the beam
at the point under
consideration.
Reinforced concrete
beams are designed to
crack in tension rather
than in compression.
This is achieved by
providing reinforcing
steel which yields
before failure of the
concrete in compression
occurs and allowing
remediation, repair, or
if necessary, evacuation
of an unsafe area
Creep
Creep is the term used
to describe the
permanent movement or
deformation of a
material in order to
relieve stresses within
the material. Concrete
which is subjected to
long-duration forces is
prone to
creep.
Short-duration forces
(such as wind or
earthquakes) do not
cause creep. Creep can
sometimes reduce the
amount of cracking that
occurs in a concrete
structure or element,
but it also must be
controlled. The amount
of primary and secondary
reinforcing in concrete
structures contributes
to a reduction in the
amount of shrinkage,
creep and cracking
Physical properties
The coefficient of
thermal expansion of
Portland cement concrete
is 0.000008 to 0.000012
(per degree Celsius)
(8-12 1/MK).[20]
The density varies, but
is around 150 pounds per
cubic foot (2400 kg/m³).[21]
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Fire
Due to its low
thermal conductivity, a layer of concrete is
frequently used for
fireproofing of steel structures. However, concrete
itself may be damaged by fire.
Up to about 300 °C, the
concrete undergoes normal
thermal expansion. Above that temperature, shrinkage
occurs due to water loss; however, the aggregate
continues expanding, which causes internal stresses. Up
to about 500 °C, the major structural changes are
carbonation and coarsening of pores. At 573 °C,
quartz undergoes rapid expansion due to
Phase transition, and at 900 °C
calcite starts shrinking due to decomposition. At
450-550 °C the cement hydrate decomposes, yielding
calcium oxide.
Calcium carbonate decomposes at about 600 °C.
Rehydration of the calcium oxide on cooling of the
structure causes expansion, which can cause damage to
material which withstood fire without falling apart.
Concrete in buildings that experienced a fire and were
left standing for several years shows extensive degree
of carbonation.
Concrete exposed to up
to 100 °C is normally considered as healthy. The parts
of a concrete structure that is exposed to temperatures
above approximately 300 °C (dependent of water/cement
ratio) will most likely get a pink color. Over
approximately 600 °C the concrete will turn light grey,
and over approximately 1000 °C it turns yellow-brown.[22]
One rule of thumb is to consider all pink colored
concrete as damaged that should be removed.
Fire will expose the
concrete to gases and liquids that can be harmful to the
concrete, among other salts and acids that occur when
gasses produced by fire come into contact with water.
Aggregate
expansion
Various types of
aggregate undergo chemical reactions in concrete,
leading to damaging expansive phenomena. The most common
are those containing reactive silica, that can react (in
the presence of water) with the alkalis in concrete (K2O
and Na2O, coming principally from cement). Among the
more reactive mineral components of some aggregates are
opal,
chalcedony,
flint and strained
quartz. Following the reaction (Alkali
Silica Reaction or ASR), an expansive gel forms,
that creates extensive cracks and damage on structural
members. On the surface of concrete pavements the ASR
can cause pop-outs, i.e. the expulsion of small cones
(up to 3 cm about in diameter) in correspondence of
aggregate particles. When some aggregates containing
dolomite are used, a dedolomitization reaction
occurs where the
magnesium carbonate compound reacts with hydroxyl
ions and yields
magnesium hydroxide and a
carbonate ion. The resulting expansion may cause
destruction of the material. Far less common are
pop-outs caused by the presence of
pyrite, an iron sulfide that generates expansion by
forming iron oxide and
ettringite. Other reactions and recrystallizations,
e.g. hydration of
clay minerals in some aggregates, may lead to
destructive expansion as well.
Sea
water effects
Concrete exposed to
sea water is susceptible to its corrosive effects.
The effects are more pronounced above the tidal zone
than where the concrete is permanently submerged. In the
submerged zone, magnesium and
hydrogen carbonate ions precipitate a layer of
brucite, about 30 micrometers thick, on which a
slower deposition of calcium carbonate as
aragonite occurs. These layers somewhat protect the
concrete from other processes, which include attack by
magnesium, chloride and sulfate ions and carbonation.
Above the water surface, mechanical damage may occur by
erosion by waves themselves or sand and gravel they
carry, and by crystallization of salts from water
soaking into the concrete pores and then drying up.
Pozzolanic cements and cements using more than 60%
of slag as aggregate are more resistant to sea water
than pure Portland cement.
Bacterial
corrosion
Bacteria themselves do
not have noticeable effect on concrete. However,
anaerobic bacteria (Thiobacillus)
in untreated sewage tend to produce
hydrogen sulfide, which is then oxidized by
aerobic bacteria present in
biofilm on the concrete surface above the water
level to
sulfuric acid which dissolves the carbonates in the
cured cement and causes strength loss. Concrete floors
lying on ground that contains
pyrite are also at risk. Using
limestone as the aggregate makes the concrete more
resistant to acids, and the sewage may be pretreated by
ways increasing pH or oxidizing or precipitating the
sulfides in order to inhibit the activity of sulfide
utilizing bacteria.
Chemical
damage
Carbonation
Carbon dioxide from air can react with the
calcium hydroxide in concrete to form
calcium carbonate. This process is called
carbonation, which is essentially the reversal of the
chemical process of
calcination of
lime taking place in a
cement kiln. Carbonation of concrete is a slow and
continuous process progressing from the outer surface
inward, but slows down with increasing diffusion depth.
Carbonation has two effects: it increases mechanical
strength of concrete, but it also decreases
alkalinity, which is essential for
corrosion prevention of the reinforcement steel.
Below a
pH
of 10, the steel's thin layer of surface passivation
dissolves and corrosion is promoted. For the latter
reason, carbonation is an unwanted process in concrete
chemistry. Carbonation can be tested by applying
Phenolphthalein solution, a
pH indicator, over a fresh fracture surface, which
indicates non-carbonated and thus alkaline areas with a
violet color.
Chlorides
Chlorides, particularly
calcium chloride, have been used to shorten the
setting time of concrete.[23]
However, calcium chloride and (to a lesser extent)
sodium chloride have been shown to leach
calcium hydroxide and cause chemical changes in
Portland cement, leading to loss of strength,[24]
as well as attacking the steel reinforcement present in
most concrete.
Sulphates
Sulphates in solution
in contact with concrete can cause chemical changes to
the cement, which can cause significant microstructural
effects leading to the weakening of the cement binder.
Distillate
Water
Distillate water can
wash out calcium content in concrete, leaving the
concrete in brittle condition. Source of distillate
water such as steam or hot water.
Leaching
Leaching is a self
healing of cracks with chemical process in concrete.
Physical damage
Damage can occur during
the casting and de-shuttering processes. For instance,
the corners of beams can be damaged during the removal
of shuttering because they are less effectively
compacted by means of vibration (improved by using
form-vibrators). Other physical damage can be caused by
the use of steel shuttering without base plates. The
steel shuttering pinches the top surface of a concrete
slab due to the weight of the next slab being
constructed.
|
Types of
Concrete
Back
to Top
Mix Design
Modern concrete mix
designs can be complex. The design of a concrete, or the
way the weights of the components of a concrete is
determined, is specified by the American Concrete
Institute, the specifications of the project, and the
building code where the project is located.
The design begins by
determining the "durability" requirements of the
concrete. These requirements take into consideration the
weather conditions (freeze-thaw) that the concrete will
be exposed to in service, and the required design
strength, or f'c, at twenty eight (28) days after
placement. The compressive strength of a concrete, fc,
is determined by taking standard molded, standard-cured,
4"x8" or 6"x12", cylinder samples.
Many factors need to be
taken into account, from the cost of the various
additives and aggregates, to the trade offs between, the
"slump" for easy mixing and placement and ultimate
performance. These factors are also specified by the
American Concrete Institute, project specifications, and
the local building code where the project is located.
A mix is then designed
using cement (Portland or other cementitious material),
coarse and fine aggregates, water and chemical
admixtures. The method of mixing will also be specified,
as well as conditions that it may be used in.
This allows a user of
the concrete to be confident that the structure will
perform properly.
Various types of
concrete have been developed for specialist application
and have become known by these names
Regular concrete is the
lay term describing concrete that is produced by
following the mixing instructions that are commonly
published on packets of cement, typically using sand or
other common material as the aggregate, and often mixed
in improvised containers. This concrete can be produced
to yield a varying strength from about 10 MPa (1450 psi)
to about 40 MPa (5800 psi), depending on the purpose,
ranging from blinding to structural concrete
respectively. Many types of pre-mixed concrete are
available which include powdered cement mixed with an
aggregate, needing only water.
Typically, a batch of
concrete can be made by using 1 part Portland cement, 2
parts dry sand, 3 parts dry stone, 1/2 part water. The
parts are in terms of weight – not volume. For example,
1-cubic-foot (0.028 m3) of concrete would be made using
22 lb (10.0 kg) cement, 10 lb (4.5 kg) water, 41 lb
(19 kg) dry sand, 70 lb (32 kg) dry stone (1/2" to 3/4"
stone). This would make 1-cubic-foot (0.028 m3) of
concrete and would weigh about 143 lb (65 kg). The sand
should be mortar or brick sand (washed and filtered if
possible) and the stone should be washed if possible.
Organic materials (leaves, twigs, etc) should be removed
from the sand and stone to ensure the highest strength.
High-strength concrete
Back to Top
High-strength concrete
has a compressive strength generally greater than 6,000
pounds per square inch (40 MPa = 5800 psi).
High-strength concrete is made by lowering the
water-cement (W/C) ratio to 0.35 or lower. Often silica
fume is added to prevent the formation of free calcium
hydroxide crystals in the cement matrix, which might
reduce the strength at the cement-aggregate bond.
Low W/C ratios and the
use of silica fume make concrete mixes significantly
less workable, which is particularly likely to be a
problem in high-strength concrete applications where
dense rebar cages are likely to be used. To compensate
for the reduced workability, superplasticizers are
commonly added to high-strength mixtures. Aggregate must
be selected carefully for high-strength mixes, as weaker
aggregates may not be strong enough to resist the loads
imposed on the concrete and cause failure to start in
the aggregate rather than in the matrix or at a void, as
normally occurs in regular concrete.
In some applications of
high-strength concrete the design criterion is the
elastic modulus rather than the ultimate compressive
strength
High-performance concrete
Back to Top
High-performance
concrete (HPC) and Ultra-high-performance concrete are
relatively new terms used to describe concrete that
conforms to a set of standards above those of the most
common applications, but not limited to strength. While
all high-strength concrete is also high-performance, not
all high-performance concrete is high-strength. Notable
concrete-mixtures are: Ductal,
concrete mixed with titanium oxide, ... Some
examples of such standards currently used in relation to
HPC are:
- Ease of
placement
- Compaction
without segregation
- Early age
strength
- Long-term
mechanical properties
- Permeability
- Density
- Heat of
hydration
- Toughness
- Volume
stability
- Long life in
severe environments
- Depending on
its implementation, environmental
[25]
Self-consolidating
concretes
Back to Top
During the 1980s a
number of countries including Japan, Sweden and France
developed concretes that are self-compacting, known as
self-consolidating concrete in the United States. This
self-consolidating concrete (SCCs) is characterized by:
- extreme fluidity
as measured by flow, typically between 650-750 mm on
a flow table, rather than slump(height)
- no need for
vibrators to compact the concrete
- placement being
easier.
- no bleed water, or
aggregate segregation
- Increased Liquid
Head Pressure, Can be detrimental to Safety and
workmanship
SCC can save up to 50%
in labor costs due to 80% faster pouring and reduced
wear and tear on
formwork.
As of 2005,
self-consolidating concretes account for 10-15% of
concrete sales in some European countries. In the US
precast concrete industry, SCC represents over 75% of
concrete production. 38 departments of
transportation in the US accept the use of SCC for
road and bridge projects.
This emerging
technology is made possible by the use of
polycarboxylates
plasticizer instead of older naphthalene based
polymers, and viscosity modifiers to address aggregate
segregation.
Shotcrete (also known
by the trade name Gunite) uses compressed air to shoot
concrete onto (or into) a frame or structure. Shotcrete
is frequently used against vertical soil or rock
surfaces, as it eliminates the need for
formwork. It is sometimes used for rock support,
especially in
tunneling. Shotcrete is also used for applications
where seepage is an issue to limit the amount of water
entering a construction site due to a high water table
or other subterranean sources. This type of concrete is
often used as a quick fix for weathering for loose soil
types in construction zones.
There are two
application methods for shotcrete.
- dry-mix – the dry
mixture of cement and aggregates is filled into the
machine and conveyed with
compressed air through the hoses. The water
needed for the hydration is added at the nozzle.
- wet-mix – the
mixes are prepared with all necessary water for
hydration. The mixes are pumped through the hoses.
At the nozzle compressed air is added for spraying.
For both methods
additives such as
accelerators and fiber reinforcement may be used.[26]
Pervious concrete contains a network of holes or
voids, to allow air or water to move through the
concrete.
This allows water to
drain naturally through it, and can both remove the
normal surface-water drainage infrastructure, and allow
replenishment of
groundwater when conventional concrete does not.
It is formed by leaving
out some or all of the fine aggregate (fines). The
remaining large aggregate then is bound by a relatively
small amount of
Portland Cement. When set, typically between 15% and
25% of the concrete volume is voids, allowing water to
drain at around 5 gal/ft²/ min or 200 L/m²/min) through
the concrete.
Aerated concrete
produced by the addition of an air entraining agent to
the concrete (or a
lightweight aggregate like
expanded clay pellets or
cork granules and
vermiculite) is sometimes called Cellular concrete,
lightweight aerated concrete, variable density concrete,
foamed concrete and lightweight or ultra-lightweight
concrete[27][28].
Not to be confused with
Aerated autoclaved concrete which is manufactured
off site using an entirely different method.
In the 1977 seminal
work on
A Pattern Language Towns, Buildings and
Construction, architect
Christopher Alexander wrote in pattern 209 on Good
Materials:
"Regular concrete is
too dense. It is heavy and hard to work. After it sets
one cannot cut into it, or nail into it. And it's
surface is ugly, cold, and hard in feeling unless
covered by expensive finishes not integral to the
structure.
And yet concrete, in
some form, is a fascinating material. It is fluid,
strong, and relatively cheap. It is available in almost
every part of the world. A University of California
professor of engineering sciences, P. Kumar Mehta, has
even just recently found a way of converting abandoned
rice husks into Portland cement.
Is there any way of
combining all these good qualities of concrete and also
having a material which is light in weight, easy to
work, with a pleasant finish? There is. It is possible
to use a whole range of ultra-lightweight concretes
which have a density and compressive strength very
similar to that of wood. They are easy to work with, can
be nailed with ordinary nails, cut with a saw, drilled
with wood-working tools, easily repaired.
We believe that
ultra-lightweight concrete is one of the most
fundamental bulk materials of the future.
The variable density is
normally described in KG per M3, where regular concrete
is 2400 kg/M3. Variable density can be as low as 300
kg/m3[29] although at
this density it would have no structural integrity at
all and would function as a filler or insulation use
only. The variable density reduces strength[30]
to increase thermal[31]
and acoustical insulation by replacing the dense heavy
concrete with air or a light material such as clay, cork
granules and vermiculite. There are many competing
products that use a foaming agent that resembles shaving
cream to mix air bubbles in with the concrete. All
accomplish the same outcome: to displace concrete with
air
Cork-cement composites
Back to Top
Waste
Cork granules are obtained during production of
bottle stoppers from the treated bark of
Cork oak.[32]
These granules have a density of about 300 kg/m³, lower
than most lightweight aggregates used for making
lightweight concrete. Cork granules do not significantly
influence cement hydration, but cork dust may.[33]
Cork cement composites have several advantages over
standard concrete, such as lower thermal conductivities,
lower densities and good energy absorption
characteristics. These composites can be made of density
from 400 to 1500 kg/m³, compressive strength from 1 to
26 MPa, and flexural strength from 0.5 to 4.0 MPa.
Roller-compacted
concrete
Back to Top
Roller-compacted
concrete, sometimes called rollcrete, is a
low-cement-content stiff concrete placed using
techniques borrowed from earthmoving and paving work.
The concrete is placed on the surface to be covered, and
is compacted in place using large heavy rollers
typically used in earthwork. The concrete mix achieves a
high density and cures over time into a strong
monolithic block.[34]
Roller-compacted concrete is typically used for concrete
pavement, but has also been used to build concrete dams,
as the low cement content causes less heat to be
generated while curing than typical for conventionally
placed massive concrete pours
The use of recycled
glass as aggregate in concrete has become popular in
modern times, with large scale research being carried
out at Columbia University in New York. This greatly
enhances the aesthetic appeal of the concrete. Recent
research findings have shown that concrete made with
recycled glass aggregates have shown better long term
strength and better thermal insulation due to its better
thermal properties of the glass aggregates.
[35]
Strictly speaking,
asphalt is a form of concrete as well, with
bituminous materials replacing cement as the binder.
Rapid strength concrete
Back to Top
This type of concrete
is able to develop high resistance within few hours
after being manufactured. This feature has advantages
such as removing the formwork early and to move forward
in the building process at record time, repair road
surfaces that become fully operational in just a few
hours.
While "rubberized
asphalt concrete" is common, rubberized Portland
cement concrete ("rubberized PCC") is still undergoing
experimental tests, as of 2007[36]
[37]
[38]
[39].
Polymer concrete is concrete which uses polymers to
bind the aggregate. Polymer concrete can gain a lot of
strength in a short amount of time. For example, a
polymer mix may reach 5000 psi in only four hours.
Polymer concrete is generally more expensive than
conventional concretes.
Geopolymer or green
concrete
Back to Top
Geopolymer concrete is a greener alternative to
ordinary Portland cement made from inorganic
aluminosilicate (Al-Si) polymer compounds that can
utilise 100% recycled industrial waste (e.g.
fly ash and
slag) as the manufacturing inputs resulting in up to
80% lower carbon dioxide emissions. Greater chemical and
thermal resistance, and better mechanical properties,
are said to be achieved by the manufacturer at both
atmospheric and extreme conditions.[40]
Similar concretes have
not only been used in
Ancient Rome (see
Roman concrete) as mentioned but also in the former
Soviet Union in the 1950s and 1960s. Buildings in
the
Ukraine are still standing after 45 years so that
this kind of formulation has a sound track record.[41]
Limecrete or lime
concrete is concrete where cement is replaced by
lime.[42]
High-temperature
applications, such as
masonry ovens and the like, generally require the
use of a
refractory cement; concretes based on Portland
cement can be damaged or destroyed by elevated
temperatures, but refractory concretes are better able
to withstand such conditions.
|
Concrete handling / Safety
precautions
Back to Top
Handling of wet
concrete must always be done with proper protective
equipment. Contact with wet concrete can cause severe
skin burns due to causticity of the mix with cement and
water.
|
Engineers usually
specify the required compressive strength of concrete,
which is normally given as the 28 day compressive
strength in megapascals (MPa) or pounds per
square inch (psi). Twenty eight days is a long wait
to determine if desired strengths are going to be
obtained, so three-day and seven-day strengths can be
useful to predict the ultimate 28-day compressive
strength of the concrete. A 25% strength gain between 7
and 28 days is often observed with 100% OPC (ordinary
Portland cement) mixtures, and up to 40% strength gain
can be realized with the inclusion of pozzolans and
supplementary cementitious materials (SCMs) such as fly
ash and/or slag cement. Strength gain depends on the
type of mixture, its constituents, the use of standard
curing, proper testing and care of cylinders in
transport, etc. It is imperative to accurately test the
fundamental properties of concrete in its fresh, plastic
state.
Concrete is typically
sampled while being placed, with testing protocols
requiring that test samples be cured under laboratory
conditions (standard cured). Additional samples may be
field cured (non-standard) for the purpose of early
'stripping' strengths, that is, form removal, evaluation
of curing, etc. but the standard cured cylinders
comprise acceptance criteria. Concrete tests can measure
the "plastic" (unhydrated) properties of concrete prior
to, and during placement. As these properties affect the
hardened compressive strength and durability of concrete
(resistance to freeze-thaw), the properties of
workability (slump/flow), temperature, density and age
are monitored to ensure the production and placement of
'quality' concrete. Tests are performed per
ASTM International,
European Committee for Standardization or
Canadian Standards Association. As measurement of
quality must represent the potential of concrete
material delivered, placed and properly cured, it is
imperative that concrete technicians performing concrete
tests are certified to do so according to these
standards.
Structural design, material design and properties
are often specified in accordance with national/regional
design codes such as
American Concrete Institute.
Compressive-strength
tests are conducted using an instrumented
hydraulic ram to compress a cylindrical or cubic
sample to failure. Tensile strength tests are conducted
either by three-point bending of a prismatic beam
specimen or by compression along the sides of a
cylindrical specimen.
|
Concrete recycling is
an increasingly common method of disposing of concrete
structures. Concrete debris was once routinely shipped
to
landfills for disposal, but recycling is increasing
due to improved environmental awareness, governmental
laws, and economic benefits.
Concrete, which must be
free of trash, wood, paper and other such materials, is
collected from demolition sites and put through a
crushing machine, often along with asphalt, bricks,
and rocks.
Reinforced concrete
contains
rebar and other metallic reinforcements, which are
removed with
magnets and recycled elsewhere. The remaining
aggregate chunks are sorted by size. Larger chunks may
go through the crusher again. Smaller pieces of concrete
are used as gravel for new construction projects.
Aggregate base gravel is laid down as the lowest
layer in a road, with fresh concrete or asphalt placed
over it. Crushed recycled concrete can sometimes be used
as the dry aggregate for brand new concrete if it is
free of contaminants, though the use of recycled
concrete limits strength and is not allowed in many
jurisdictions. On
March 3,
1983, a government funded research team (the VIRL
research.codep) approximated that almost 17% of
worldwide landfill was by-products of concrete based
waste.
Recycling concrete
provides environmental benefits, conserving landfill
space and use as
aggregate reduces the need for
gravel mining.
|
Use of
concrete in infrastructure
Back to Top
Mass concrete structures
These include
gravity dams such as the
Itaipu,
Hoover Dam and the
Three Gorges Dam and large
breakwaters. Concrete that is poured all at once in
one block (so that there are no weak points where the
concrete is "welded" together) is used for tornado
shelters.
Concrete Textures
Back to Top
When one thinks of
concrete, oftentimes the image of a dull, gray concrete
wall comes to mind. Nevertheless, with the use of
formliner, concrete can be cast and molded into
different textures. Sound/retaining walls, bridges,
office buildings and more serve as the optimal canvases
for concrete art.
For example, the Pima
Freeway/Loop 101 retaining and sound walls in
Scottsdale, Arizona, feature desert flora and fauna, a
67-foot lizard and 40-foot cacti along the 8-mile
stretch. The project, titled "The Path Most Traveled,"
is one example of how concrete can be shaped using
elastomeric
formliner.
Reinforced concrete
structures
Back to Top
Reinforced concrete
contains steel reinforcing that is designed and placed
in structural members at specific positions to cater for
all the stress conditions that the member is required to
accommodate.
Prestressed concrete
structures
Back to Top
Prestressed concrete is
a form of reinforced concrete which builds in
compressive stresses during construction to oppose
those found when in use. This can greatly reduce the
weight of beams or slabs, by better distributing the
stresses in the structure to make optimal use of the
reinforcement.
For example a
horizontal beam will tend to sag down. If the
reinforcement along the bottom of the beam is
prestressed, it can counteract this.
In pre-tensioned
concrete, the prestressing is achieved by using steel or
polymer tendons or bars that are subjected to a tensile
force prior to casting, or for post-tensioned concrete,
after casting.
Concrete Paving to Lower
City Temperatures
Back to Top
Using light-colored
concrete has proven effective in reflecting up to 50%
more light than asphalt and reducing ambient
temperature.[43]
A low albedo value, characteristic of black asphalt,
absorbs a large percentage of solar heat and contributes
to the warming of cities. By paving with light colored
concrete, in addition to replacing asphalt with
light-colored concrete, communities can lower their
average temperature.[44]
Many U.S. cities show
that pavement comprise approximately 30-40% of their
surface area.[43]
This directly impacts the temperature of the city, as
demonstrated by the urban-heat-island effect. In
addition to decreasing the overall temperature of
parking lots and large paved areas by paving with
light-colored concrete, there are supplemental benefits.
One example is 10-30% improved nighttime visibility.[43]
The potential of energy saving within an area is also
high. With lower temperatures, the demand for air
conditioning decreases, saving vast amounts of energy.
Atlanta has tried to
mitigate the heat-island effect. City officials noted
that when using heat-reflecting concrete, their average
city temperature decreased by 6 °F.[45]
New York City offers another example. The Design Trust
for Public Space in New York City found that by slightly
raising the albedo value in their city, beneficial
effects such as energy savings could be achieved. It was
concluded that this could be accomplished by the
replacement of black asphalt with light-colored
concrete.[44]
|
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Concrete
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Building Code Requirements for Structural
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ISBN 0870312642.
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13,
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-
^
http://www.litebuilt.com/table1.html
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^
http://www.litebuilt.com/table2.html
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^
http://www.litebuilt.com/table3.html
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^
Gibson, L.J. &
Ashby, M.F. 1999. Cellular Solids: Structure
and Properties; 2nd Edition (Paperback),
Cambridge Uni. Press. pp.453-467.
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^
Karade S.R., Irle M.A., Maher K. 2006. Influence
of granule properties and concentration on
cork-cement compatibility. Holz als Roh- und
Werkstoff. 64: 281–286 (DOI
10.1007/s00107-006-0103-2).
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^
Roller-Compacted Concrete (RCC) Pavements |
Portland Cement Association (PCA)
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^
http://www.sciencedirect.com/science?_ob=ArticleListURL&_method=list&_ArticleListID=687884626&_sort=d&view=c&_acct=C000014338&_version=1&_urlVersion=0&_userid=208107&md5=63a74de0d7e38203d0fc8dbb3107393c
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^
Crumb Rubber Concrete - Precast Solutions
Magazine Fall 2004
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^
Emerging Construction Technologies
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^
ASU researcher puts recalled Firestone tires to
good use
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^
Experimental Study on Strength, Modulus of
Elasticity, and Damping Ratio of Rubberized
Concrete
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^
Zeobond is one such manufacturer that has
built and operates the world’s first geopolymer
concrete plant for the local Australian market
with several additional plants coming online in
Asia and North America in 2008. According to
this manufacturer its E-Crete branded
concrete can be used in all applications where
concrete is used today.
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^
Green Cement ABC Catalyst program first
broadcast 22 May 2008.
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^
An Investigation Into The Feasibility Of Timber
And Limecrete Composite Flooring
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^
a
b
c
"Cool Pavement Report" (PDF).
Environmental Protection Agency. June 2005.
http://www.epa.gov/heatisland/resources/pdf/CoolPavementReport_Former%20Guide_complete.pdf.
Retrieved on 2009-02-06.
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^
a
b
Gore, A; Steffen, A (2008). World Changing: A
User's Giode for the 21st Century. New York:
Abrams. pp. 258.
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^
"Concrete facts". Pacific Southwest Concrete
Alliance.
http://www.concreteresources.net/categories/4F26A962-D021-233F-FCC5EF707CBD860A/fun_facts.html.
Retrieved on 2009-02-06.
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(978) 939-5712
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